Recycling rare earth elements is hard. Science is trying to make it easieron January 24, 2023 at 9:18 pm

Our modern lives depend on rare earth elements, and someday soon we may not have enough to meet growing demand.

Because of their special properties, these 17 metallic elements are crucial ingredients in computer screens, cell phones and other electronics, compact fluorescent lamps, medical imaging machines, lasers, fiber optics, pigments, polishing powders, industrial catalysts – the list goes on and on (SN Online: 1/16/23). Notably rare earths are an essential part of the high-powered magnets and rechargeable batteries in the electric vehicles and renewable energy technologies needed to get the world to a low- or zero-carbon future.

In 2021, the world mined 280,000 metric tons of rare earths — roughly 32 times as much as was mined in the mid-1950s. And demand is only going to increase. By 2040, experts estimate, we’ll need up to seven times as much rare earths as we do today.

Satisfying that appetite won’t be easy. Rare earth elements are not found in concentrated deposits. Miners must excavate huge amounts of ore, subject it to physical and chemical processes to concentrate the rare earths, and then separate them. The transformation is energy intensive and dirty, requiring toxic chemicals and often generating a small amount of radioactive waste that must be safely disposed of. Another concern is access: China has a near monopoly on both mining and processing; the United States has just one active mine (SN Online: 1/1/23).

For most of the jobs rare earths do, there are no good substitutes. So to help meet future demand and diversify who controls the supply — and perhaps even make rare earth recovery “greener” — researchers are looking for alternatives to conventional mining.

Proposals include everything from extracting the metals from coal waste to really out-there ideas like mining the moon. But the approach most likely to make an immediate dent is recycling. “Recycling is going to play a very important and central role,” says Ikenna Nlebedim, a materials scientist at Ames National Laboratory in Iowa and the Department of Energy’s Critical Materials Institute. “That’s not to say we’re going to recycle our way out of the critical materials challenge.”

Still, in the rare earth magnets market, for instance, by about 10 years from now, recycling could satisfy as much as a quarter of the demand for rare earths, based on some estimates. “That’s huge,” he says.

But before the rare earths in an old laptop can be recycled as regularly as the aluminum in an empty soda can, there are technological, economic and logistical obstacles to overcome.

Why are rare earths so challenging to extract?

Recycling seems like an obvious way to get more rare earths. It’s standard practice in the United States and Europe to recycle from 15 to 70 percent of other metals, such as iron, copper, aluminum, nickel and tin. Yet today, only about 1 percent of rare earth elements in old products are recycled, says Simon Jowitt, an economic geologist at the University of Nevada, Las Vegas.

“Copper wiring can be recycled into more copper wiring. Steel can just be recycled into more steel,” he says. But a lot of rare earth products are “inherently not very recyclable.”

Rare earths are often blended with other metals in touch screens and similar products, making removal difficult. In some ways, recycling rare earths from tossed-out items resembles the challenge of extracting them from ore and separating them from each other. Traditional rare earth recycling methods also require hazardous chemicals such as hydrochloric acid and a lot of heat, and thus a lot of energy. On top of the environmental footprint, the cost of recovery may not be worth the effort given the small yield of rare earths. A hard disk drive, for instance, might contain just a few grams; some products offer just milligrams.

Chemists and materials scientists, though, are trying to develop smarter recycling approaches. Their techniques put microbes to work, ditch the acids of traditional methods or attempt to bypass extraction and separation.

Microbial partners can help recycle rare earths

One approach leans on microscopic partners. Gluconobacter bacteria naturally produce organic acids that can pull rare earths, such as lanthanum and cerium, from spent catalysts used in petroleum refining or from fluorescent phosphors used in lighting. The bacterial acids are less environmentally harmful than hydrochloric acid or other traditional metal-leaching acids, says Yoshiko Fujita, a biogeochemist at Idaho National Laboratory in Idaho Falls. Fujita leads research into reuse and recycling at the Critical Materials Institute. “They can also be degraded naturally,” she says.

In experiments, the bacterial acids can recover only about a quarter to half of the rare earths from spent catalysts and phosphors. Hydrochloric acid can do much better — in some cases extracting as much as 99 percent. But bio-based leaching might still be profitable, Fujita and colleagues reported in 2019 in ACS Sustainable Chemistry & Engineering.

In a hypothetical plant recycling 19,000 metric tons of used catalyst a year, the team estimated annual revenues to be roughly $1.75 million. But feeding the bacteria that produce the acid on-site is a big expense. In a scenario in which the bacteria are fed refined sugar, total costs for producing the rare earths are roughly $1.6 million a year, leaving around just $150,000 in profits. Switching from sugar to corn stalks, husks and other harvest leftovers, however, would slash costs by about $500,000, raising profits to about $650,000.

One experimental recycling approach uses organic acids made by bacteria to extract rare earths from waste products. This reactor at the Idaho National Laboratory prepares an organic acid mixture for such recycling.IDAHO NATIONAL LAB

Other microbes can also help extract rare earths and take them even further. A few years ago, researchers discovered that some bacteria that metabolize rare earths produce a protein that preferentially grabs onto these metals. This protein, lanmodulin, can separate rare earths from each other, such as neodymium from dysprosium — two components of rare earth magnets. A lanmodulin-based system might eliminate the need for the many chemical solvents typically used in such separation. And the waste left behind — the protein — would be biodegradable. But whether the system will pan out on a commercial scale is unknown.

How to pull rare earths from discarded magnets

Another approach already being commercialized skips the acids and uses copper salts to pull the rare earths from discarded magnets, a valuable target. Neodymium-iron-boron magnets are about 30 percent rare earth by weight and the single largest application of the metals in the world. One projection suggests that recovering the neodymium in magnets from U.S. hard disk drives alone could meet up about 5 percent of the world’s demand outside of China before the end of the decade.

Nlebedim led a team that developed a technique that uses copper salts to leach rare earths out of shredded electronic waste that contains magnets. Dunking the e-waste in a copper salt solution at room temperature dissolves the rare earths in the magnets. Other metals can be scooped out for their own recycling, and the copper can be reused to make more salt solution. Next, the rare earths are solidified and, with the help of additional chemicals and heating, transformed into powdered minerals called rare earth oxides. The process, which has also been used on material left over from magnet manufacturing that typically goes to waste, can recover 90 to 98 percent of the rare earths, and the material is pure enough to make new magnets, Nlebedim’s team has demonstrated.

In a best-case scenario, using this method to recycle 100 tons of leftover magnet material might produce 32 tons of rare earth oxides and net more than $1 million in profits, an economic analysis of the method suggests.

That study also evaluated the approach’s environmental impacts. Compared with producing one kilogram of rare earth oxide via one of the main types of mining and processing currently used in China, the copper salt method has less than half the carbon footprint. It produces an average of about 50 kilograms of carbon dioxide equivalent per kilogram of rare earth oxide versus 110, Nlebedim’s team reported in 2021 in ACS Sustainable Chemistry & Engineering.

But it’s not necessarily greener than all forms of mining. One sticking point is that the process requires toxic ammonium hydroxide and roasting, which consumes a lot of energy, and it still releases some carbon dioxide. Nlebedim’s group is now tweaking the technique. “We want to decarbonize the process and make it safer,” he says.

Meanwhile, the technology seems promising enough that TdVib, an Iowa company that designs and manufactures magnetic materials and products, has licensed it and built a pilot plant. The initial aim is to produce two tons of rare earth oxides per month, says Daniel Bina, TdVib’s president and CEO. The plant will recycle rare earths from old hard disk drives from data centers.

Noveon Magnetics, a company in San Marcos, Texas, is already making recycled neodymium-iron-boron magnets. In typical magnet manufacturing, the rare earths are mined, transformed into metal alloys, milled into a fine powder, magnetized and formed into a magnet. Noveon knocks out those first two steps, says company CEO Scott Dunn.

After demagnetizing and cleaning discarded magnets, Noveon directly mills them into a powder before building them back up as new magnets. Unlike with other recycling methods, there’s no need to extract and separate the rare earths out first. The final product can be more than 99 percent recycled magnet, Dunn says, with a small addition of virgin rare earth elements — the “secret sauce,” as he puts it — that allows the company to fine-tune the magnets’ attributes.

Compared with traditional magnet mining and manufacturing, Noveon’s method cuts energy use by about 90 percent, Miha Zakotnik, Noveon’s chief technology officer, and other researchers reported in 2016 in Environmental Technology & Innovation. Another 2016 analysis estimated that for every kilogram of magnet produced via Noveon’s method, about 12 kilograms of carbon dioxide equivalent are emitted. That’s about half as much of the greenhouse gas as conventional magnets.

Dunn declined to share what volume of magnets Noveon currently produces or how much its magnets cost. But the magnets are being used in some industrial applications, for pumps, fans and compressors, as well as some consumer power tools and other electronics.

To help with recycling, Apple developed the robot Daisy (shown), which can dismantle 23 models of iPhones. Other robots in the works — Taz and Dave — will specialize in recovering rare earth magnets.APPLE

Rare earth recycling has logistical hurdles

Even as researchers clear technological hurdles, there are still logistical barriers to recycling. “We don’t have the systems for collecting end-of-life products that have rare earths in them,” Fujita says, “and there’s the cost of dismantling those products.” For a lot of e-waste, before rare earth recycling can begin, you have to get to the bits that contain those precious metals.

Noveon has a semiautomated process for removing magnets from hard disk drives and other electronics.

Apple is also trying to automate the recycling process. The company’s Daisy robot can dismantle iPhones. And in 2022, Apple announced a pair of robots called Taz and Dave that facilitate the recycling of rare earths. Taz can gather magnet-containing modules that are typically lost during the shredding of electronics. Dave can recover magnets from taptic engines, Apple’s technology for providing users with tactile feedback when, say, tapping an iPhone screen.

Even with robotic aids, it would still be a lot easier if companies just designed products in a way that made recycling easy, Fujita says.

No matter how good recycling gets, Jowitt sees no getting around the need to ramp up mining to feed our rare earth–hungry society. But he agrees recycling is necessary. “We’re dealing with intrinsically finite resources,” he says. “Better we try and extract what we can rather than just dumping it in the landfill.”

Source: Sciencenews.org

The post Recycling rare earth elements is hard. Science is trying to make it easier appeared first on Energy News Beat.

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